Optimizing Hydrogen Storage and Fuel Cell Performance Using Carbon-Based Materials: Insights into Pressure and Surface Area Effects

Abstract

This is a paper from web nothing original Efficient hydrogen storage is critical for advancing hydrogen-based technologies. This study investigates the effects of pressure and surface area on hydrogen storage in three carbon-based materials: graphite, graphene oxide, and reduced graphene oxide. Hydrogen adsorption–desorption experiments under pressures ranging from 1 to 9 bar revealed nonlinear storage capacity responses, with optimal performance at around 5 bar. The specific surface area plays a pivotal role, with reduced graphene oxide and exhibiting a surface area of 70.31 m2/g, outperforming graphene oxide (33.75 m2/g) and graphite (7.27 m2/g). Reduced graphene oxide achieved the highest hydrogen storage capacity, with 768 sccm and a 3 wt.% increase over the other materials. In assessing proton-exchange fuel cell performance, this study found that increased hydrogen storage correlates with enhanced power density, with reduced graphene oxide reaching a maximum of 0.082 W/cm2, compared to 0.071 W/cm2 for graphite and 0.017 W/cm2 for graphene oxide. However, desorption rates impose temporal constraints on fuel cell operation. These findings enhance our understanding of pressure–surface interactions and underscore the balance between hydrogen storage capacity, surface area, and practical performance in carbon-based materials, offering valuable insights for hydrogen storage and fuel cell applications