Catalysis of thiophene hydrogenolysis by bimetallic sulfide catalysts of differentV N, Rodin and Benjaram M, Reddy and V V, Rao and A V, Kalinkin and A N, Startsev (1989) Catalysis of thiophene hydrogenolysis by bimetallic sulfide catalysts of different. Reaction Kinetics and Catalysis Letters, 40 (1). pp. 71-76.
AbstractThe activity of sulfide catalysts MI/SiO2, MI/WS2, (MI,W)/SiO2 and (Ni,MII)/SiO2 (MI is a first row transition metal, and MII=Nb, Mo, W or Re) in the thiophene hydrogenolysis reaction has been studied. Activities of mono- and bimetallic catalysts are found to change in the same manner depending upon the nature of MI. The formation of a sulfide bimetallic species (SBMS) is suggested
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