Enantioselective aminolytic kinetic resolution (AKR) of epoxides catalyzed by recyclable polymeric Cr(III) salen complexes

R I, Kureshy and Surendra, Singh and N H, Khan and S.H.R., Abdi and Santosh , Agrawal and R V , Jasra (2006) Enantioselective aminolytic kinetic resolution (AKR) of epoxides catalyzed by recyclable polymeric Cr(III) salen complexes. Tetrahedron: Asymmetry , 17 (11). pp. 1638-1643.

PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
150Kb

Official URL: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THT-4KBVV76-1&_user=518931&_coverDate=07%2F17%2F2006&_alid=589647082&_rdoc=6&_fmt=full&_orig=search&_cdi=5291&_sort=d&_docanchor=&view=c&_ct=28&_acct=C000025838&_version=1&_urlVersion=0&_userid=51

Abstract

Polymeric chiral Cr(III) salen complexes catalyzed regio-, diastereo-, and enantioselective aminolytic kinetic resolution (AKR) of trans-stilbene oxide, trans-β-methyl styrene oxide, and 6-CN-chromene oxide proceeded smoothly at room temperature, providing the desired anti-β-amino alcohols in high yields and enantiomeric excess (up to 100%).

Item Type:	Article
Subjects:	Science > Chemistry
ID Code:	922
Deposited By:	Prof Balasubramanian Viswanathan
Deposited On:	16 Jun 2007 15:00
Last Modified:	16 Jun 2007 15:00

Repository Staff Only: item control page