Catalysis Database

Hydrogen transfer reactions IV. Substituent effect in the reduction of benzaldehydes by isopropyl alcohol catalyzed by alumina

N, Venkatasubramanian and D V, Ramana and C N, Pillai (1978) Hydrogen transfer reactions IV. Substituent effect in the reduction of benzaldehydes by isopropyl alcohol catalyzed by alumina. Journal of Catalysis , 51 (1). pp. 40-46.

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Official URL: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6WHJ-4CFW537-G6&_user=518931&_coverDate=01%2F31%2F1978&_alid=587484242&_rdoc=61&_fmt=full&_orig=search&_cdi=6852&_sort=d&_docanchor=&view=c&_ct=72&_acct=C000025838&_version=1&_urlVersion=0&_userid=

Abstract

A linear Hammett correlation is reported for the reduction of substituted benzaldehydes by isopropyl alcohol catalyzed by alumina containing 2.2% (by weight) sodium ions, at 300 °C in the vapor phase. The positive nature of the slope supports the hydrid transfer mechanism proposed for this reduction.

Item Type:Article
Subjects:Science > Chemistry
ID Code:878
Deposited By:Prof Balasubramanian Viswanathan
Deposited On:11 Jun 2007 16:46
Last Modified:11 Jun 2007 16:46

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