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somerization of allyl alcohol in the presence of Raney nickel

J V N, Vara Prasad and A G, Samuelson and C N, Pillai (1982) somerization of allyl alcohol in the presence of Raney nickel. Journal of Catalysis , 75 (1). pp. 1-6.

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Official URL: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6WHJ-4CFVG25-9K&_user=518931&_coverDate=05%2F31%2F1982&_alid=587484242&_rdoc=56&_fmt=full&_orig=search&_cdi=6852&_sort=d&_docanchor=&view=c&_ct=72&_acct=C000025838&_version=1&_urlVersion=0&_userid=

Abstract

Allyl alcohol was found to isomerize to propanal in the presence of Raney nickel. By means of deuterium labeling studies it was concluded that the reaction involves a 1,3-sigmatropic migration of hydrogen from C1 to C3 to form the enol of propanal.

Item Type:Article
Subjects:Science > Chemistry
ID Code:874
Deposited By:Prof Balasubramanian Viswanathan
Deposited On:11 Jun 2007 16:26
Last Modified:11 Jun 2007 16:26

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