Reaction of carboxylic acids with carbonyl compounds over aluminaM, Jayamani and C N, Pillai (1984) Reaction of carboxylic acids with carbonyl compounds over alumina. Journal of Catalysis , 87 (1). pp. 93-97.
AbstractAs part of a study to elucidate the mechanism of the ketonization of carboxylic acid, the reactions of carboxylic acids with carbonyl compounds over alumina at 350–400 °C were studied. Products arising from the transfer of alkyl group of the carboxylic acid to the carbonyl compounds as well as those arising from a Perkin-type condensation of carboxylic acid with carbonyl compound were detected. Mechanisms of these reactions are discussed.
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