Catalysis Database

Simultaneous adsorption of hydrogen and carbon monoxide on zinc oxide

T S, Nagarjunan and M V C , Sastri and J.C , Kuriacose (1963) Simultaneous adsorption of hydrogen and carbon monoxide on zinc oxide. Journal of Catalysis , 2 (3). pp. 223-229.

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Official URL: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6WHJ-4CFW1JT-9Y&_user=518931&_coverDate=06%2F30%2F1963&_alid=587048893&_rdoc=33&_fmt=full&_orig=search&_cdi=6852&_sort=d&_docanchor=&view=c&_ct=33&_acct=C000025838&_version=1&_urlVersion=0&_userid=

Abstract

The simultaneous adsorption of carbon monoxide and hydrogen on zinc oxide was investigated at −46 °, 0 °, and 25 °C, using gas mixtures of composition 1 CO:1 H2 and 1 CO:2 H2. At 0 ° and 25 °C there was mutual enhancement in the adsorption of gases while at −46 °C the adsorption was the same as with the pure gases. It is suggested that in mixed adsorption two processes take place, namely, the creation of sites by one gas for the adsorption of the other and the formation of complexes of the type =CHOH in the adsorbed phase.

Item Type:Article
Subjects:Science > Chemistry
ID Code:856
Deposited By:Prof Balasubramanian Viswanathan
Deposited On:10 Jun 2007 11:51
Last Modified:10 Jun 2007 11:51

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