Deactivation of RuCl2(PPh3)3 during disproportionation of D-glucose in amide solvents

S , Rajagopal and S, Vancheesan and J, Rajaram and J.C , Kuriacose (1983) Deactivation of RuCl2(PPh3)3 during disproportionation of D-glucose in amide solvents. Journal of Molecular Catalysis , 22 (2). pp. 131-135.

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Abstract

The catalyst RuCl2(PPh3)3 is transformed into a catalytically inactive complex RuCl2(CO)(PPh3)2(DMF) during disproportionation of D-glucose in dimethylformamide (DMF). In dimethylacetamide (DMA), the catalyst is converted to RuCl2(CO)(PPh3)2(DMA) and cis-RuCl2(CO)2(PPh3)2. The aldehydo-glucose is shown to be the main source of carbon monoxide.

Item Type:	Article
Subjects:	Science > Chemistry
ID Code:	845
Deposited By:	Prof Balasubramanian Viswanathan
Deposited On:	10 Jun 2007 11:03
Last Modified:	10 Jun 2007 11:03

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