Catalysis Database
Login | Create Account

Silica supported MoO3: a mild heterogeneous catalyst for the Beckmann rearrangement and its application to some sugar derived ketoximes

Mohan K , Dongare and V V, Bhagwat and C V, Ramana and M K, Gurjar (2004) Silica supported MoO3: a mild heterogeneous catalyst for the Beckmann rearrangement and its application to some sugar derived ketoximes. Tetrahedron Letters., 45 (24). pp. 4759-4762.

[img]PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
263Kb

Abstract

Silica supported molybdenum(VI) oxide (20%) has been explored as a new solid catalyst for the Beckmann rearrangement and the results are compared in parallel with the known β-zeolite as a catalyst for the same transformation. Both catalysts were found to facilitate the rearrangement under mild conditions and the conditions employed were tolerable for protecting groups such as isopropylidene, cyclohexylidene and PMB are commonly employed in carbohydrate chemistry

Item Type:Article
Subjects:Science > Chemistry
ID Code:643
Deposited By:Dr S Navaladian
Deposited On:22 Apr 2007 12:13
Last Modified:22 Apr 2007 12:13

Repository Staff Only: item control page

Catalysis Database is powered by EPrints 3 which is developed by the School of Electronics and Computer Science at the University of Southampton. More information and software credits.