Ch, Subrahmanyam and B, Louis and B, Viswanathan and A, Renken and T.K, Varadarajan (2005) Synthesis, characterisation and catalytic properties of vanadium substituted mesoporous aluminophosphates. Applied Catalysis A: General, 282 . pp. 67-71.
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Abstract
Vanadium substituted mesoporous AlPO have been synthesised using structure-directing surfactant under hydrothermal synthesis conditions. The presence of V in the framework of AlPO has been established by ESR, XPS, UV–vis DRS and ICP-AES measurements. This system is capable of promoting the oxidation of toluene to aldehyde and benzoic acid when the oxidising agent is 70% tert-butyl hydroperoxide while with 30% H2O2 cresols are formed. The activity of V-AlPO has been compared with those obtained with other similar porous materials like V-MCM 48, V-MCM-41, V-Al-Beta and VS-1.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 56 |
| Deposited By: | INVALID USER |
| Deposited On: | 24 Feb 2007 15:00 |
| Last Modified: | 24 Feb 2007 15:00 |
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