P.S, Raghavan and Veda , Ramaswamy and T.T, Upadhya and A. , Sudalai and A.V., Ramaswamy and S., Sivasanker (1997) Selective catalytic oxidation of thioethers to sulfoxides over Mo-silicalite- 1 ( MoS- 1) molecular sieves. Journal of Molecular Catalysis A: Chemical , 122 . pp. 75-80.
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Abstract
Mo-containing silicalite-1 (MFI) samples with Si/Mo (mole) ratios in the range 80 to 300 have been synthesized hydrothemally and were characterized by different physico-chemical techniques such as SEM, XRD, BET, TG/DTA, FlIR, XPS, UV-visible spectra. The catalyst was found to be active for the chemoselective oxidation of various thioethers to the corresponding sulfoxides, without generation of sulfones, using 30% H,O, as the oxidant.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 510 |
| Deposited By: | INVALID USER |
| Deposited On: | 01 Apr 2007 19:38 |
| Last Modified: | 06 Apr 2007 17:56 |
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