Catalysis -- Paul H_Emmet -- Volume II -- Fundamental Priciples (Part 2) -- Revised Edition--1961

Abstract

CATALYSIS VOLUME II FUNDAMENTAL PRINCIPLES (PART 2)----------------------- Edited by PAUL H. EMMETT Gulf Research and Development Company’s Multiple Fellowship Mellon Institute, Pittsburgh, Pennsylvania ----------------------- Contributing Authors Henry Eyring Hugh M. Hulburt W. B. Innes Edward L. King Ransom B. Parlin Merrill B. Wallenstein Ahlborn Wheeler Bruno J. Zwolinski ----------------------- CONTENTS 1. Classification of Heterogeneous Catalytic Vapor Phase Reactions, W. B. Innes. 1 Acid-Catalyzed Reactions. 2 Hydrogenation-Dehydrogenation. 24 Oxidation. 61 Halogenation and Dehalogenation. 78 Hydration and Dehydration. 79 Dehydration-Dehydrogenation. 83 Catalytic Exchange Reactions. 88 Miscellaneous Reactions. 88 ----------------------- 2. Reaction Rates and Selectivity in Catalyst Pores, Ahlborn Wheeler. 165 Introduction. 105 The Importance and Origin of Catalyst Pore Structure. 106 Experimental Methods for Investigating Pore Structure 108 A Working Model of the Pore Structure. 124 Mechanism of Diffusion and Flow in Catalyst Pores. . 126 Reaction Rates on Porous Catalysts. 131 Pressure and Temperature Gradients in Single Catalyst Pellets. 1^1 Comparison with the Work of Thiele and Others. 145 Comparison of Theory with Experiment (Application to Practical Reactions). 1^6 Reaction Rates on Poisoned Catalysts—(Apparent Se¬ lective Poisoning). 161 Effect of Pore Structure on Catalyst Selectivity. 158 ----------------------- 3. The Nature of Catalytic Surfaces, Hugh M. Hulburt... 167 Introduction. ^67 Electronic Structure ofSolids. 167 Metals. Semiconductors. Dislocations. Surface States in SoUds. ----------------------- 4. Nature of Complexes on Catalyst Surfaces, Hugh M. Hulburt. Nature of Surface Complexes on Catalyst Surfaces. . . 233 Heterogeneity of Catalyst Surfaces. 2o8 PureMetals. PromotedMetals. 243 OxideCatalysts. 247 ----------------------- 5. General Theories of Heterogeneous Catalysis, Ransom B. Parlin, Merrill B. Wallenstein, Bruno J. Zwolinski, and Henry Eyring. 255 Introduction. 255 Adsorption—IdealCase. 258 Adsorption—NonidealCase. 275 Energetics of Adsorption and Reaction. 283 Nature of the Activated Complex. 306 Nature of the Catalyst. 321 ----------------------- 6. Catalysis in Homogeneous Reactions in a Liquid Phase, Edward L. King. 337 Theories of Reaction Kinetics. 338 Rate Laws and Reaction Mechanisms. 340 MediumEffects. 346 Acid and Base Catalysis. 389 The Influence of Complexing Agents Upon Reaction Velocity. 416 Negative Catalysis. 447 ----------------------- AuthorIndex. 457 SubjectIndex. 469