J, Gopalakrishnan and B, Viswanathan and V, Srinivasan (1970) Preparation and thermal decomposition of some oxomolybdenum(vi) oxalates. Journal of Inorganic and Nuclear Materials , 32 . pp. 2565-2568.
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Abstract
Anionic oxomolybdenum(Vl) oxalates having the general formula A2[MoO3(C204)] • H20 where A = K + or NH4 + are prepared, characterized by chemical analysis and infrared spectra and their thermal decomposition studied by DTA and TGA. A chain structure containing MoOe octahedra linked through oxygen is proposed for the complex oxalates on the basis of i.r, absorption spectra. The ammonium compound decomposes endothermally around 270°C to give lower oxides of molybdenum which are finally oxidised to MOO3, while the final decomposition product of the potassium compound is K2MoO4.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 440 |
| Deposited By: | INVALID USER |
| Deposited On: | 22 Mar 2007 12:15 |
| Last Modified: | 22 Mar 2007 12:15 |
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