Joseph, Trissa and S.S , Deshpande and S., Sivasanker and A. , Vinu and S , Ernst and M, Hartmann (2003) Hydrogenation of olefins over hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex immobilized on functionalized MCM-41 and SBA-15. Journal of Molecular Catalysis A: Chemical , 206 . pp. 13-21.
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Abstract
Hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex [RuHCl(CO)(PPh3)3] has been immobilized inside the pores of amine functionalized MCM-41 and SBA-15 materials. These grafted complexes were characterized by XRD, FTIR, N2 adsorption measurements, XPS and tested as catalyst for the hydrogenation of olefins. Immobilization and pore size has marked effects on the catalytic activity in the hydrogenation of olefins and the complex immobilized on functionalized SBA-15 was found to be catalytically more active than the one immobilized on MCM-41.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| ID Code: | 298 |
| Deposited By: | INVALID USER |
| Deposited On: | 02 Mar 2007 04:02 |
| Last Modified: | 19 Mar 2007 06:31 |
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