M.M., Taqui Khan and S.B., Halligudi and S.H.R., Abdi (1988) An efficient water-soluble ruthenium hydroformylation catalyst for the exclusive formation of l-heptaldehyde from l-hexene. Journal of Molecular Catalysis , 48 . pp. 313-317.
PDF
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
314kB |
Abstract
Hydroformylation of l-hexene was carried out in a high pressure reactor using water soluble [Ru(III)-EDTA] catalyst, synthesis gas (1: 1) CO + H2 at 50 atm, in 80:20 ethanol-water mixture and at 130“C. The reaction proceeds with a turnover rate of 11.83 mol product per mol catalyst per hour with the conversion of 1-hexene exclusively (100%) to linear l-heptaldehyde.
Item Type: | Article |
---|---|
Subjects: | Science > Chemistry |
ID Code: | 289 |
Deposited By: | INVALID USER |
Deposited On: | 01 Mar 2007 19:37 |
Last Modified: | 20 Mar 2007 20:53 |
Repository Staff Only: item control page