M.M., Taqui khan and S.B., Halligudi and S.H.R., Abdi (1988) Hydroformylation of allyl alchohol catalyzed by water-soluble Ru(III)-EDTA complex. Journal of Molecular Catalysis, 45 . pp. 215-224.
![[img]](http://catalysis.eprints.iitm.ac.in/style/images/fileicons/application_pdf.png) |
PDF
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
653kB |
Abstract
Hydroformylation of ally1 alcohol was studied in aqueous medium using [Ru(III)-EDTA] complex as catalyst and (1:l) CO + H2 gas in a high pressure autoclave at pressures upto 50 atm and in the temperature range 90 - 130“C. The hydroformylation of ally1 alcohol gives gamma-hydroxybutyraldehyde as the primary product, along with the side products gamma-butyrolactone, dihydrofuran and 1,4-butanediol. The hydroformylation of allyl alcohol is first order with respect to ally1 alcohol and catalyst concentrations, and has a linear dependence on CO + H2 (1:l) pressure of the syngas. The activation energy of the reaction is found to be 23.13 kcal mol-1.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 282 |
| Deposited By: | INVALID USER |
| Deposited On: | 01 Mar 2007 14:50 |
| Last Modified: | 01 Mar 2007 14:58 |
Repository Staff Only: item control page
