Debabra, Chatterjee and H.C., Bajaj and S.B., Halligudi and K.N., Bhatt (1993) Catalysis of alkene hydrogenation and oxidation by nickel-saloph complex; a novel bifunctional catalyst. Journal of Molecular Catalysis , 84 . L1-L5.
![[img]](http://catalysis.eprints.iitm.ac.in/style/images/fileicons/application_pdf.png) |
PDF
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
357kB |
Abstract
Hydrogenation of cyclohexene to cyclohexane and cyclooctene to cyclooctane with H2 in presence of Ni (saloph ), 1, (saloph = bis(salicylaldehyde )-o-phenylenediamine) were carried out at moderately high pressure (60 atm ) and temperature (50 ’ C ) in ethanol medium. At normal temperature and pressure, the same catalyst (complex 1) catalyses the epoxidation of cyclohexene and cyclooctene with KHSO5 in presence of CTAB (cetyl trimethyl ammonium bromide; a phasetransfer reagent) in CH2Cl2. Cyclohexene oxide and cyclooctene oxide were found to be the major products of the epoxidation reactions.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 278 |
| Deposited By: | INVALID USER |
| Deposited On: | 01 Mar 2007 12:39 |
| Last Modified: | 01 Mar 2007 12:39 |
Repository Staff Only: item control page
