J. , Sudhakar Reddy and S. , Sivasanker and P. , Ratnasamy (1992) Hydroxylation of phenol over TS-2, a titanium silicate molecular sieve. Journal of Molecular Catalysis, 71 . pp. 373-381.
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Abstract
The influence of different process parameters on the hydroxylation of phenol with H202 over the titanium silicate molecular sieve TS-2 has been investigated. Apart from the primary products v/s., p- and o dihydroxybenzenes, the corresponding quinones are also formed. Higher Ti contents in the catalyst (TS-2) and higher catalyst concentrations lower the formation of the secondary oxidation products. Solvents have an influence on the relative amounts of the two dihydroxybenzenes in the product. H202 efficiency of up to 74% is obtainable at ~ 2896 phenol conversion to dihydroxybenzenes.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 150 |
| Deposited By: | INVALID USER |
| Deposited On: | 28 Feb 2007 13:31 |
| Last Modified: | 28 Feb 2007 13:31 |
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