P. , Karandikar, and K.C , Dhanya and S.S , Deshpande and A.J. , Chandwadkar and S., Sivasanker and M. , Agashe (2004) Cu/Co-salen immobilized MCM-41: characterization and catalytic reactions. Catalysis Communications , 5 . pp. 69-74.
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Abstract
Copper and cobalt (salen) complexes immobilized on the walls of MCM-41 modified with aminopropyl groups have been synthesized and characterized by various physico-chemical measurements such as XRD, FTIR, UV–Vis, EPR, TGA. UV–Vis and FTIR spectra reveal adduct formation of metal–salen complexes with the amino groups tethered to the SiO2 surface. EPR studies indicate molecular dispersion of the salen complex inside the pores of MCM-41. The activity of the immobilized complexes as catalyst for the liquid phase oxidation of olefins was investigated.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 120 |
| Deposited By: | INVALID USER |
| Deposited On: | 28 Feb 2007 11:12 |
| Last Modified: | 18 Mar 2007 18:19 |
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