A., Thangaraj and S., Sivasanker and P., Ratnasamy (1991) Catalytic properties of crystalline titanium silicalites III. Ammoximation of cyclohexanone. Journal of Catalysis , 131 . pp. 394-400.
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Abstract
The ammoximation of cyclohexanone to cyclohexanone oxime over the titanium silicalite TS-1 with NH3 and HzO2 is reported. The ammoximation takes place at conversions exceeding 90% with selectivities greater than 99%. The influence of various catalyst and process parameters on the oximation reaction is reported, By-products from condensation reactions become significant at low concentrations of H202 and NH3. Possible mechanisms for the formation of the oxime and byproducts are reported.
| Item Type: | Article |
|---|---|
| Subjects: | Science > Chemistry |
| ID Code: | 114 |
| Deposited By: | INVALID USER |
| Deposited On: | 28 Feb 2007 10:42 |
| Last Modified: | 20 Mar 2007 22:00 |
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