Catalysis Database

Selectivity dependence on the alloying element of carbon supported Pt-alloy catalysts in the hydrogenation of phenol

S T, Srinivas and L, Jhansi Lakshmi and P, Kanta Rao (1994) Selectivity dependence on the alloying element of carbon supported Pt-alloy catalysts in the hydrogenation of phenol. Applied Catalysis A: General , 110 (2). pp. 167-172.

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Official URL: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TF5-43VCJR5-19&_user=518931&_coverDate=03%2F31%2F1994&_alid=606058388&_rdoc=25&_fmt=full&_orig=search&_cdi=5217&_sort=d&_docanchor=&view=c&_ct=55&_acct=C000025838&_version=1&_urlVersion=0&_userid=

Abstract

Single step vapour phase hydrogenation of phenol over Pt-M/C (M = Cr, V and Zr) alloy catalysts was investigated at atmospheric pressure and 200°C. The alloying element shows a significant effect on the product selectivities. While Pt-Cr/C and Pt-V/C catalysts are highly selective for hydrogenation of phenol to cyclohexanone, the Pt-Zr/C catalysts are predominantly selective to cyclohexanol.

Item Type:Article
Uncontrolled Keywords:alloys; phenol hydrogenation; platinum; selectivity (cyclohexanol/cyclohexanone)
Subjects:Science > Chemistry
ID Code:1007
Deposited By:Prof Balasubramanian Viswanathan
Deposited On:05 Aug 2007 11:40
Last Modified:05 Aug 2007 11:40

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